From http://www.centos.org/docs/5/html/Deployment_Guide-en-US/s1-dhcp-configuring-client.html

To configure a DHCP client manually, modify the /etc/sysconfig/network file to enable networking and the configuration file for each network device in the /etc/sysconfig/network-scripts directory. In this directory, each device should have a configuration file named ifcfg-eth0, where eth0 is the network device name.

The /etc/sysconfig/network file should contain the following line:

NETWORKING=yes

The NETWORKING variable must be set to yes if you want networking to start at boot time.

The /etc/sysconfig/network-scripts/ifcfg-eth0 file should contain the following lines:

DEVICE=eth0
BOOTPROTO=dhcp
ONBOOT=yes

A configuration file is needed for each device to be configured to use DHCP.